Ammonia Removal Using Emulsion Liquid Membrane Research
Explore a novel study on ammonia removal using palm-oil based Emulsion Liquid Membrane (ELM) and synergistic carrier optimization for wastewater treatment.
FACULTY OF CHEMICAL AND<br>ENERGY ENGINEERING
FINAL YEAR PROJECT I | SEMESTER 2 2025/2026
AMMONIA REMOVAL USING<br>EMULSION LIQUID MEMBRANE
MUHAMAD FAHMI RIYONO
Bachelor of Chemical Engineering
Supervised by: Dr. Shuhada Atika Binti Idrus Saidi
June 2026
PRESENTATION OUTLINE
Introduction & Problem Background
Problem Statement
Research Objectives & Scope
Literature Review
ELM Process & Mechanism
Methodology
Expected Results
Conclusion & Significance
OUTLINE
01
CHAPTER 1
INTRODUCTION
PROBLEM BACKGROUND
WHY IS THIS A CONCERN?
<ul style="margin: 0; padding-left: 20px; list-style-type: none;"> <li style="margin-bottom: 16px; position: relative;"> <span style="position: absolute; left: -30px; color: #C8922A; font-size: 32px; line-height: 28px;">•</span> <strong style="color: #611825;">Ammonia (NH₃)</strong> — carbon-free, hydrogen-rich chemical essential for food safety & clean energy </li> <li style="margin-bottom: 16px; position: relative;"> <span style="position: absolute; left: -30px; color: #C8922A; font-size: 32px; line-height: 28px;">•</span> <strong style="color: #611825;">Generated from:</strong> fertilizer production, petroleum refining, manufacturing & food processing </li> <li style="margin-bottom: 16px; position: relative;"> <span style="position: absolute; left: -30px; color: #C8922A; font-size: 32px; line-height: 28px;">•</span> <strong style="color: #611825;">In wastewater:</strong> exists as ammonium ions (NH₄⁺) and dissolved ammonia (NH₃) — <span style="font-style: italic;">pH-dependent</span> </li> <li style="margin-bottom: 0; position: relative;"> <span style="position: absolute; left: -30px; color: #C8922A; font-size: 32px; line-height: 28px;">•</span> <strong style="color: #611825;">Excessive discharge causes:</strong> eutrophication, oxygen depletion, aquatic toxicity </li> </ul>
<ul style="margin: 0; padding-left: 20px; list-style-type: none;"> <li style="margin-bottom: 16px; position: relative;"> <span style="position: absolute; left: -30px; color: #C8922A; font-size: 32px; line-height: 28px;">•</span> Stricter environmental regulations demand efficient ammonia removal technologies </li> <li style="margin-bottom: 0; position: relative;"> <span style="position: absolute; left: -30px; color: #C8922A; font-size: 32px; line-height: 28px;">•</span> High ammonia affects water quality and poses health risks to humans </li> </ul>
02
CHAPTER 1
PROBLEM STATEMENT
CONVENTIONAL METHODS & LIMITATIONS
THE GAP
THE SOLUTION: ELM
03
CHAPTER 1
RESEARCH OBJECTIVES & SCOPE
OBJECTIVE 1
To determine the most suitable single carrier for ammonia extraction in the ELM process.
<b>Carriers screened:</b> D2EHPA, Cyanex 272, TOA, TBP
<b>Concentration range:</b> 0.1 – 0.5 M each
<b>Fixed conditions:</b> Span 80 surfactant, H₂SO₄ stripping agent, treat ratio, mixing speed
<b>Measurement:</b> UV-Vis spectrophotometry
<b>Efficiency formula:</b> RE(%) = (Ci – Cf)/Ci × 100
OBJECTIVE 2
To investigate the effects of synergistic carrier formulation using ELM for ammonia extraction.
<b>Base carrier:</b> D2EHPA (0.1 – 0.2 M)
<b>Synergist carriers:</b> Cyanex 272, TBP, TOA (0.01 – 0.1 M each)
Compare synergistic vs single carrier performance
04
CHAPTER 2
LITERATURE REVIEW
AMMONIA PROPERTIES
Molecular Weight
17.03 g/mol
Boiling Point
-33.35°C
Freezing Point
-77.7°C
Density
0.771 g/L
Color
Colorless
pKa (25°C)
9.25
NH₃(aq) + H₂O ⇌ NH₄⁺(aq) + OH⁻(aq)
<span style="color:#7B1C2E;font-weight:700;">At HIGH pH</span> → NH₃ (toxic free ammonia)
<span style="color:#7B1C2E;font-weight:700;">At LOW pH</span> → NH₄⁺ (ionized, less toxic)
AMMONIA SOURCES
<strong style="color:#7B1C2E;">Agriculture:</strong> fertilizer production, ammonia volatilization (27–41% N losses)
<strong style="color:#7B1C2E;">Industry:</strong> petroleum refining, food processing, manufacturing
Agriculture accounts for ~88% of UK ammonia emissions (UK CEH, 2023)
ENVIRONMENTAL IMPACTS
<strong style="color:#7B1C2E;">Eutrophication</strong> → algal blooms → oxygen depletion
<strong style="color:#7B1C2E;">Aquatic toxicity</strong> — fish gill damage, respiratory failure
<strong style="color:#7B1C2E;">Human health</strong> risks from contaminated water
04
CHAPTER 2 — LITERATURE REVIEW
CONVENTIONAL REMOVAL METHODS
BIOLOGICAL TREATMENT
High removal efficiency
Environmentally friendly
Low chemical consumption
~50% total energy for aeration
Long retention times
High operational costs
AIR STRIPPING (Physical)
Simple operation
Highly effective
Wide industrial application
Dependent on pH & temperature
Scaling, foaming, corrosion
Alkaline chemical addition costs
ION EXCHANGE (Chemical)
High selectivity
Enables ammonium recovery
Simple application
Competing cations reduce efficiency
Resin fouling & frequent regeneration
High operational cost
→ All methods have significant limitations, justifying the need for ELM technology
05
CHAPTER 2
EMULSION LIQUID MEMBRANE (ELM)
WHAT IS ELM?
Water-in-Oil-in-Water (W/O/W) double emulsion system where solute (ammonia) is transported from external feed phase → through liquid membrane phase → into internal stripping phase.
EXTERNAL PHASE
Wastewater containing NH₃ (feed)
Carrier transports NH₃
MEMBRANE PHASE
Palm oil + Span 80 + Carrier (D2EHPA/synergist)
NH₃ stripped & trapped
INTERNAL PHASE
H₂SO₄ stripping agent
High interfacial area for mass transfer
Simultaneous extraction & stripping
Low energy consumption (ambient T & P)
No expensive pre-treatment
No sludge generation
High efficiency for low solute concentration
Small solvent volume required
Globules 0.1–2mm; Internal droplets 0.1–10 μm
05
CHAPTER 2 — ELM PROCESS
ELM COMPONENTS
CARRIER
Role: Facilitates NH₃ transport across the membrane phase
DILUENT — PALM OIL
(Green Alternative)
STRIPPING AGENT — H₂SO₄
CHAPTER 3
METHODOLOGY
06
06
CHAPTER 3 — METHODOLOGY
EXPERIMENTAL FLOWCHART
START
Preparation of Solutions
External Feed Phase<br><span style="font-size: 15px; opacity: 0.9;">(NH<sub>4</sub>Cl)</span>
Internal Phase<br><span style="font-size: 15px; opacity: 0.9;">(H<sub>2</sub>SO<sub>4</sub>)</span>
Membrane Phase<br><span style="font-size: 15px; opacity: 0.9;">(Palm oil + Span 80 + Carrier)</span>
W/O Preparation<br><span style="font-size: 15px; opacity: 0.95; font-weight: 600;">High Speed Homogenizer (5,000–20,000 rpm)</span>
W/O Emulsion Formed
W/O/W Preparation<br><span style="font-size: 15px; opacity: 0.95; font-weight: 600;">Disperse into External Phase<br>(250 rpm, treat ratio 0.08–0.16)</span>
Separation Process<br><span style="font-size: 16px; opacity: 0.95; font-weight: 600;">Settling funnel, 15–30 min</span>
UV-Vis Spectrophotometry<br><span style="font-size: 16px; opacity: 0.95; font-weight: 600;">Measure remaining NH<sub>3</sub></span>
Calculate Removal Efficiency<br><span style="font-size: 16px; opacity: 0.95; font-weight: 600;">RE(%) = (C<sub>i</sub> − C<sub>f</sub>) / C<sub>i</sub> × 100</span>
END
07
CHAPTER 4
EXPECTED RESULTS
1
SINGLE CARRIER EFFECT
Different ammonia removal efficiencies expected for each carrier (D2EHPA, TOA, TBP, Cyanex)
One carrier anticipated to show superior performance due to stronger NH₃ interaction
Will identify optimal single carrier type and concentration
2
SYNERGISTIC CARRIER EFFECT
D2EHPA + synergist (Cyanex/TBP/TOA) expected to outperform single carriers
Synergism improves solubility, enhances mass transfer
Prior study: D2EHPA + Aliquat 336 → up to 90% efficiency (Othman et al., 2020)
3
EFFECT OF DILUENT (PALM OIL)
Palm oil expected to perform comparably to petroleum-based diluents
Green alternative: biodegradable, low toxicity, renewable
Prior study: palm oil ELM → ~99% extraction efficiency (Björkegren et al., 2015)
Novel contribution: first study of palm oil ELM for ammonia removal
4
EFFECT OF STRIPPING AGENT
H₂SO₄ as internal phase reagent captures NH₃ effectively via chemical reaction
Optimal concentration: ~0.18 M H₂SO₄
Expected efficiency: ~98% at optimum conditions (Şişmek & Altaş, 2022)
Higher concentration beyond optimum may reduce performance
08
CONCLUSION
SIGNIFICANCE & CONTRIBUTION
RESEARCH SUMMARY
This study investigates Emulsion Liquid Membrane (ELM) technology using palm oil as a green diluent and H₂SO₄ as stripping agent for efficient ammonia removal from wastewater. Synergistic carrier formulations (D2EHPA + Cyanex/TBP/TOA) are evaluated to maximise extraction efficiency.
ALIGNMENT WITH UN SDGs
SDG 6 — CLEAN WATER & SANITATION
SDG 6.3: Reduce water pollution, eliminate dumping, minimise hazardous chemicals
Provides efficient ammonia removal technology for industrial compliance
SDG 14 — LIFE BELOW WATER
Reduces ammonia discharge into aquatic ecosystems
Prevents eutrophication and protects marine life
SDG 9 — INDUSTRY INNOVATION
Advances green ELM technology with renewable diluent (palm oil)
Novel synergistic carrier approach for sustainable wastewater treatment
KEY CONTRIBUTIONS
First study of palm oil-based ELM for ammonia removal
Novel synergistic carrier formulation approach
Sustainable, low-energy alternative to conventional methods
Supports environmental regulations and water quality standards
REF
REFERENCES
KEY REFERENCES
1. Björkegren, S. et al. (2015). A new emulsion liquid membrane based on a palm oil for the extraction of heavy metals. <i>Membranes</i>, 5(2), 168–179.
2. Othman, N. et al. (2020). Synergism of Aliquat336-D2EHPA as carrier on selectivity of organic compound dyes extraction via emulsion liquid membrane. <i>Journal of Hazardous Materials</i>, 389, 121904.
3. Şişmek, E. & Altaş, L. (2022). Ammonium removal from wastewater by ELM. [Reference for 98% efficiency at 0.18 M H₂SO₄]
4. Ye, Y. et al. (2025). Research progress on biological denitrification process in wastewater treatment. <i>Water</i>, 17(4), 520.
5. Prajapati, J. C. et al. (2014). Removal of Ammonia from Wastewater by Ion Exchange Technology. <i>IJIRT</i>, 1(9).
6. Raval, A. R. et al. (2022). A Comprehensive Review on Green Emulsion Liquid Membrane. <i>Water Air & Soil Pollution</i>, 233(379).
7. IEA. (2021). Ammonia Technology Roadmap. International Energy Agency.
8. Cameron, K. C. et al. (2013). Nitrogen losses from the soil/plant system: A review. <i>Annals of Applied Biology</i>, 162(2), 145–173.
9. Jusoh, N., Othman, N. & Rosly, M. B. (2021). Extraction and recovery of organic compounds via ELM. <i>Journal of Environmental Chemical Engineering</i>.
10. Admawi, H. K. & Mohammed, A. A. (2023). A comprehensive review of ELM for toxic contaminants removal. <i>Journal of Environmental Chemical Engineering</i>, 11(3).
THANK YOU
Questions & Discussion
- ammonia-removal
- chemical-engineering
- wastewater-treatment
- emulsion-liquid-membrane
- green-technology
- palm-oil
- carrier-optimization